| DATE | HOME | SCORE | AWAY | ||||
| 06.10.2007 |  | VALENCIA | 1-2 | ESPANYOL |  | ||
| 07.10.2007 |  | REAL ZARAGOZA | 3-0 | LEVANTE |  | ||
| 07.10.2007 |  | SEVILLA | 0-1 | DEPORTIVO LA CORUÑA |  | ||
| 07.10.2007 |  | REAL MADRID | 2-0 | RECREATIVO HUELVA |  | ||
| 07.10.2007 |  | OSASUNA | 3-2 | VILLARREAL |  | ||
| 07.10.2007 |  | REAL MURCIA | 0-0 | REAL BETIS |  | ||
| 07.10.2007 |  | MALLORCA | 4-2 | GETAFE |  | ||
| 07.10.2007 |  | BARCELONA | 3-0 | ATLÉTICO MADRID |  | ||
| 07.10.2007 |  | ATHLETIC BILBAO | 1-1 | ALMERÍA |  | ||
| 07.10.2007 |  | RACING SANTANDER | 2-0 | REAL VALLADOLID |  |
