| DATE | HOME | SCORE | AWAY | ||||
| 29.09.2007 |  | REAL ZARAGOZA | 2-0 | SEVILLA |  | ||
| 29.09.2007 |  | LEVANTE | 1-4 | BARCELONA |  | ||
| 30.09.2007 |  | VILLARREAL | 1-0 | ATHLETIC BILBAO |  | ||
| 30.09.2007 |  | REAL VALLADOLID | 1-4 | REAL MURCIA |  | ||
| 30.09.2007 |  | ESPANYOL | 1-0 | DEPORTIVO LA CORUÑA |  | ||
| 30.09.2007 |  | REAL BETIS | 3-0 | MALLORCA |  | ||
| 30.09.2007 |  | ATLÉTICO MADRID | 2-0 | OSASUNA |  | ||
| 30.09.2007 |  | ALMERÍA | 0-1 | RACING SANTANDER |  | ||
| 30.09.2007 |  | GETAFE | 0-1 | REAL MADRID |  | ||
| 30.09.2007 |  | RECREATIVO HUELVA | 0-1 | VALENCIA |  |
