| DATE | HOME | SCORE | AWAY | ||||
| 25.09.2007 |  | SEVILLA | 2-3 | ESPANYOL |  | ||
| 26.09.2007 |  | VALENCIA | 2-1 | GETAFE |  | ||
| 26.09.2007 |  | RACING SANTANDER | 0-2 | VILLARREAL |  | ||
| 26.09.2007 |  | OSASUNA | 4-1 | LEVANTE |  | ||
| 26.09.2007 |  | REAL MURCIA | 0-1 | ALMERÍA |  | ||
| 26.09.2007 |  | MALLORCA | 4-2 | REAL VALLADOLID |  | ||
| 26.09.2007 |  | DEPORTIVO LA CORUÑA | 0-2 | RECREATIVO HUELVA |  | ||
| 26.09.2007 |  | ATHLETIC BILBAO | 0-2 | ATLÉTICO MADRID |  | ||
| 26.09.2007 |  | BARCELONA | 4-1 | REAL ZARAGOZA |  | ||
| 27.09.2007 |  | REAL MADRID | 2-0 | REAL BETIS |  |
