| DATE | HOME | SCORE | AWAY | ||||
| 22.09.2007 |  | RECREATIVO HUELVA | 2-1 | ESPANYOL |  | ||
| 22.09.2007 |  | BARCELONA | 2-1 | SEVILLA |  | ||
| 23.09.2007 |  | REAL ZARAGOZA | 2-1 | OSASUNA |  | ||
| 23.09.2007 |  | VILLARREAL | 2-0 | REAL MURCIA |  | ||
| 23.09.2007 |  | LEVANTE | 1-2 | ATHLETIC BILBAO |  | ||
| 23.09.2007 |  | GETAFE | 0-0 | DEPORTIVO LA CORUÑA |  | ||
| 23.09.2007 |  | REAL BETIS | 1-2 | VALENCIA |  | ||
| 23.09.2007 |  | ALMERÍA | 1-1 | MALLORCA |  | ||
| 23.09.2007 |  | ATLÉTICO MADRID | 4-0 | RACING SANTANDER |  | ||
| 23.09.2007 |  | REAL VALLADOLID | 1-1 | REAL MADRID |  |
