| DATE | HOME | SCORE | AWAY | ||||
| 15.09.2007 |  | VALENCIA | 2-1 | REAL VALLADOLID |  | ||
| 15.09.2007 |  | REAL MADRID | 3-1 | ALMERÍA |  | ||
| 15.09.2007 |  | ATHLETIC BILBAO | 1-1 | REAL ZARAGOZA |  | ||
| 16.09.2007 |  | ESPANYOL | 1-0 | GETAFE |  | ||
| 16.09.2007 |  | RACING SANTANDER | 1-0 | LEVANTE |  | ||
| 16.09.2007 |  | REAL MURCIA | 1-1 | ATLÉTICO MADRID |  | ||
| 16.09.2007 |  | MALLORCA | 0-1 | VILLARREAL |  | ||
| 16.09.2007 |  | DEPORTIVO LA CORUÑA | 1-0 | REAL BETIS |  | ||
| 16.09.2007 |  | SEVILLA | 4-1 | RECREATIVO HUELVA |  | ||
| 16.09.2007 |  | OSASUNA | 0-0 | BARCELONA |  |
