| DATE | HOME | SCORE | AWAY | ||||
| 20.10.2007 |  | VILLARREAL | 3-1 | BARCELONA |  | ||
| 20.10.2007 |  | LEVANTE | 0-2 | SEVILLA |  | ||
| 20.10.2007 |  | DEPORTIVO LA CORUÑA | 2-4 | VALENCIA |  | ||
| 20.10.2007 |  | ESPANYOL | 2-1 | REAL MADRID |  | ||
| 21.10.2007 |  | REAL VALLADOLID | 1-2 | ATHLETIC BILBAO |  | ||
| 21.10.2007 |  | RECREATIVO HUELVA | 0-2 | MALLORCA |  | ||
| 21.10.2007 |  | GETAFE | 2-0 | REAL MURCIA |  | ||
| 21.10.2007 |  | REAL BETIS | 1-1 | RACING SANTANDER |  | ||
| 21.10.2007 |  | ALMERÍA | 2-0 | OSASUNA |  | ||
| 21.10.2007 |  | ATLÉTICO MADRID | 4-0 | REAL ZARAGOZA |  |
