| DATE | HOME | SCORE | AWAY | ||||
| 25.02.2006 |  | ATLÉTICO MADRID | 5-0 | MÁLAGA |  | ||
| 25.02.2006 |  | REAL ZARAGOZA | 0-2 | BARCELONA |  | ||
| 26.02.2006 |  | VALENCIA | 1-1 | GETAFE |  | ||
| 26.02.2006 |  | REAL BETIS | 2-0 | REAL SOCIEDAD |  | ||
| 26.02.2006 |  | CELTA DE VIGO | 2-0 | CÁDIZ |  | ||
| 26.02.2006 |  | ESPANYOL | 5-0 | SEVILLA |  | ||
| 26.02.2006 |  | ATHLETIC BILBAO | 1-1 | VILLARREAL |  | ||
| 26.02.2006 |  | DEPORTIVO ALAVÉS | 2-2 | RACING SANTANDER |  | ||
| 26.02.2006 |  | MALLORCA | 2-1 | REAL MADRID |  | ||
| 26.02.2006 |  | OSASUNA | 1-2 | DEPORTIVO LA CORUÑA |  |
