| DATE | HOME | SCORE | AWAY | ||||
| 18.02.2006 |  | VILLARREAL | 4-0 | ESPANYOL |  | ||
| 18.02.2006 |  | BARCELONA | 5-1 | REAL BETIS |  | ||
| 18.02.2006 |  | REAL MADRID | 3-0 | DEPORTIVO ALAVÉS |  | ||
| 18.02.2006 |  | SEVILLA | 1-0 | CELTA DE VIGO |  | ||
| 19.02.2006 |  | CÁDIZ | 1-3 | OSASUNA |  | ||
| 19.02.2006 |  | DEPORTIVO LA CORUÑA | 1-1 | REAL ZARAGOZA |  | ||
| 19.02.2006 |  | REAL SOCIEDAD | 1-2 | VALENCIA |  | ||
| 19.02.2006 |  | GETAFE | 0-3 | ATLÉTICO MADRID |  | ||
| 19.02.2006 |  | MÁLAGA | 0-2 | MALLORCA |  | ||
| 19.02.2006 |  | RACING SANTANDER | 0-1 | ATHLETIC BILBAO |  |
