| DATE | HOME | SCORE | AWAY | ||||
| 04.03.2006 |  | BARCELONA | 3-2 | DEPORTIVO LA CORUÑA |  | ||
| 04.03.2006 |  | CÁDIZ | 2-0 | ESPANYOL |  | ||
| 04.03.2006 |  | REAL MADRID | 2-1 | ATLÉTICO MADRID |  | ||
| 04.03.2006 |  | VILLARREAL | 3-2 | DEPORTIVO ALAVÉS |  | ||
| 05.03.2006 |  | CELTA DE VIGO | 2-0 | OSASUNA |  | ||
| 05.03.2006 |  | GETAFE | 1-0 | REAL BETIS |  | ||
| 05.03.2006 |  | MÁLAGA | 0-0 | VALENCIA |  | ||
| 05.03.2006 |  | RACING SANTANDER | 0-0 | MALLORCA |  | ||
| 05.03.2006 |  | REAL SOCIEDAD | 1-3 | REAL ZARAGOZA |  | ||
| 05.03.2006 |  | SEVILLA | 2-1 | ATHLETIC BILBAO |  |
