| DATE | HOME | SCORE | AWAY | ||||
| 21.09.2005 |  | VILLARREAL | 1-2 | CELTA DE VIGO |  | ||
| 21.09.2005 |  | SEVILLA | 0-0 | CÁDIZ |  | ||
| 21.09.2005 |  | REAL ZARAGOZA | 3-1 | OSASUNA |  | ||
| 21.09.2005 |  | DEPORTIVO LA CORUÑA | 1-1 | REAL BETIS |  | ||
| 21.09.2005 |  | BARCELONA | 2-2 | VALENCIA |  | ||
| 21.09.2005 |  | REAL SOCIEDAD | 3-2 | ATLÉTICO MADRID |  | ||
| 21.09.2005 |  | GETAFE | 1-1 | MALLORCA |  | ||
| 21.09.2005 |  | MÁLAGA | 0-0 | DEPORTIVO ALAVÉS |  | ||
| 21.09.2005 |  | RACING SANTANDER | 1-0 | ESPANYOL |  | ||
| 22.09.2005 |  | REAL MADRID | 3-1 | ATHLETIC BILBAO |  |
