| DATE | HOME | SCORE | AWAY | ||||
| 17.09.2005 |  | VALENCIA | 2-2 | DEPORTIVO LA CORUÑA |  | ||
| 17.09.2005 |  | MALLORCA | 5-2 | REAL SOCIEDAD |  | ||
| 18.09.2005 |  | REAL BETIS | 0-0 | REAL ZARAGOZA |  | ||
| 18.09.2005 |  | CÁDIZ | 1-1 | VILLARREAL |  | ||
| 18.09.2005 |  | CELTA DE VIGO | 0-1 | RACING SANTANDER |  | ||
| 18.09.2005 |  | ESPANYOL | 1-0 | REAL MADRID |  | ||
| 18.09.2005 |  | ATHLETIC BILBAO | 1-2 | MÁLAGA |  | ||
| 18.09.2005 |  | DEPORTIVO ALAVÉS | 3-4 | GETAFE |  | ||
| 18.09.2005 |  | ATLÉTICO MADRID | 2-1 | BARCELONA |  | ||
| 18.09.2005 |  | OSASUNA | 1-0 | SEVILLA |  |
