| DATE | HOME | SCORE | AWAY | ||||
| 10.09.2005 |  | REAL MADRID | 2-3 | CELTA DE VIGO |  | ||
| 10.09.2005 |  | REAL BETIS | 1-0 | OSASUNA |  | ||
| 10.09.2005 |  | DEPORTIVO LA CORUÑA | 1-0 | ATLÉTICO MADRID |  | ||
| 11.09.2005 |  | VILLARREAL | 1-1 | SEVILLA |  | ||
| 11.09.2005 |  | REAL ZARAGOZA | 2-2 | VALENCIA |  | ||
| 11.09.2005 |  | BARCELONA | 2-0 | MALLORCA |  | ||
| 11.09.2005 |  | REAL SOCIEDAD | 2-1 | DEPORTIVO ALAVÉS |  | ||
| 11.09.2005 |  | GETAFE | 1-1 | ATHLETIC BILBAO |  | ||
| 11.09.2005 |  | MÁLAGA | 1-2 | ESPANYOL |  | ||
| 11.09.2005 |  | RACING SANTANDER | 0-1 | CÁDIZ |  |
