| DATE | HOME | SCORE | AWAY | ||||
| 24.09.2005 |  | VALENCIA | 2-1 | REAL SOCIEDAD |  | ||
| 24.09.2005 |  | REAL BETIS | 1-4 | BARCELONA |  | ||
| 24.09.2005 |  | REAL ZARAGOZA | 1-1 | DEPORTIVO LA CORUÑA |  | ||
| 24.09.2005 |  | ESPANYOL | 1-2 | VILLARREAL |  | ||
| 24.09.2005 |  | ATLÉTICO MADRID | 0-1 | GETAFE |  | ||
| 25.09.2005 |  | DEPORTIVO ALAVÉS | 0-3 | REAL MADRID |  | ||
| 25.09.2005 |  | MALLORCA | 1-4 | MÁLAGA |  | ||
| 25.09.2005 |  | OSASUNA | 2-0 | CÁDIZ |  | ||
| 25.09.2005 |  | ATHLETIC BILBAO | 0-0 | RACING SANTANDER |  | ||
| 25.09.2005 |  | CELTA DE VIGO | 2-1 | SEVILLA |  |
