| DATE | HOME | SCORE | AWAY | ||||
| 06.05.2006 |  | BARCELONA | 2-0 | ESPANYOL |  | ||
| 06.05.2006 |  | MÁLAGA | 0-2 | SEVILLA |  | ||
| 06.05.2006 |  | VALENCIA | 1-1 | ATLÉTICO MADRID |  | ||
| 07.05.2006 |  | REAL BETIS | 2-1 | MALLORCA |  | ||
| 07.05.2006 |  | DEPORTIVO LA CORUÑA | 1-2 | ATHLETIC BILBAO |  | ||
| 07.05.2006 |  | GETAFE | 3-1 | CÁDIZ |  | ||
| 07.05.2006 |  | RACING SANTANDER | 2-1 | OSASUNA |  | ||
| 07.05.2006 |  | REAL SOCIEDAD | 2-2 | CELTA DE VIGO |  | ||
| 07.05.2006 |  | REAL MADRID | 3-3 | VILLARREAL |  | ||
| 07.05.2006 |  | REAL ZARAGOZA | 3-0 | DEPORTIVO ALAVÉS |  |
