| DATE | HOME | SCORE | AWAY | ||||
| 03.05.2006 |  | ATHLETIC BILBAO | 1-0 | REAL ZARAGOZA |  | ||
| 03.05.2006 |  | ATLÉTICO MADRID | 0-1 | OSASUNA |  | ||
| 03.05.2006 |  | CÁDIZ | 2-2 | REAL SOCIEDAD |  | ||
| 03.05.2006 |  | CELTA DE VIGO | 0-1 | BARCELONA |  | ||
| 03.05.2006 |  | DEPORTIVO ALAVÉS | 2-0 | REAL BETIS |  | ||
| 03.05.2006 |  | ESPANYOL | 1-2 | DEPORTIVO LA CORUÑA |  | ||
| 03.05.2006 |  | MALLORCA | 2-1 | VALENCIA |  | ||
| 03.05.2006 |  | SEVILLA | 3-0 | GETAFE |  | ||
| 03.05.2006 |  | VILLARREAL | 2-1 | MÁLAGA |  | ||
| 04.05.2006 |  | RACING SANTANDER | 2-3 | REAL MADRID |  |
