| DATE | HOME | SCORE | AWAY | ||||
| 14.01.2006 |  | REAL BETIS | 1-0 | ATLÉTICO MADRID |  | ||
| 14.01.2006 |  | VALENCIA | 2-0 | OSASUNA |  | ||
| 15.01.2006 |  | REAL ZARAGOZA | 3-1 | MALLORCA |  | ||
| 15.01.2006 |  | DEPORTIVO LA CORUÑA | 0-2 | DEPORTIVO ALAVÉS |  | ||
| 15.01.2006 |  | BARCELONA | 2-1 | ATHLETIC BILBAO |  | ||
| 15.01.2006 |  | REAL SOCIEDAD | 0-1 | ESPANYOL |  | ||
| 15.01.2006 |  | GETAFE | 1-1 | CELTA DE VIGO |  | ||
| 15.01.2006 |  | MÁLAGA | 0-2 | CÁDIZ |  | ||
| 15.01.2006 |  | REAL MADRID | 4-2 | SEVILLA |  | ||
| 15.01.2006 |  | RACING SANTANDER | 1-0 | VILLARREAL |  |
