| DATE | HOME | SCORE | AWAY | ||||
| 07.01.2006 |  | ATHLETIC BILBAO | 1-2 | DEPORTIVO LA CORUÑA |  | ||
| 07.01.2006 |  | ESPANYOL | 1-2 | BARCELONA |  | ||
| 08.01.2006 |  | VILLARREAL | 0-0 | REAL MADRID |  | ||
| 08.01.2006 |  | SEVILLA | 3-1 | MÁLAGA |  | ||
| 08.01.2006 |  | CÁDIZ | 1-0 | GETAFE |  | ||
| 08.01.2006 |  | CELTA DE VIGO | 1-0 | REAL SOCIEDAD |  | ||
| 08.01.2006 |  | DEPORTIVO ALAVÉS | 0-2 | REAL ZARAGOZA |  | ||
| 08.01.2006 |  | MALLORCA | 1-1 | REAL BETIS |  | ||
| 08.01.2006 |  | ATLÉTICO MADRID | 0-0 | VALENCIA |  | ||
| 08.01.2006 |  | OSASUNA | 1-1 | RACING SANTANDER |  |
