| DATE | HOME | SCORE | AWAY | ||||
| 29.10.2005 |  | REAL BETIS | 0-2 | REAL MADRID |  | ||
| 29.10.2005 |  | ATHLETIC BILBAO | 1-1 | CELTA DE VIGO |  | ||
| 30.10.2005 |  | VALENCIA | 1-1 | RACING SANTANDER |  | ||
| 30.10.2005 |  | REAL ZARAGOZA | 1-1 | MÁLAGA |  | ||
| 30.10.2005 |  | DEPORTIVO LA CORUÑA | 1-0 | GETAFE |  | ||
| 30.10.2005 |  | BARCELONA | 5-0 | REAL SOCIEDAD |  | ||
| 30.10.2005 |  | DEPORTIVO ALAVÉS | 0-0 | CÁDIZ |  | ||
| 30.10.2005 |  | MALLORCA | 1-1 | SEVILLA |  | ||
| 30.10.2005 |  | ATLÉTICO MADRID | 1-1 | VILLARREAL |  | ||
| 30.10.2005 |  | OSASUNA | 2-0 | ESPANYOL |  |
