| DATE | HOME | SCORE | AWAY | ||||
| 25.09.2004 |  | ATLÉTICO MADRID | 1-0 | VILLARREAL |  | ||
| 25.09.2004 |  | ATHLETIC BILBAO | 2-1 | REAL MADRID |  | ||
| 25.09.2004 |  | DEPORTIVO LA CORUÑA | 1-1 | REAL BETIS |  | ||
| 26.09.2004 |  | OSASUNA | 2-1 | GETAFE |  | ||
| 26.09.2004 |  | ESPANYOL | 1-0 | MÁLAGA |  | ||
| 26.09.2004 |  | NUMANCIA | 0-0 | ALBACETE |  | ||
| 26.09.2004 |  | MALLORCA | 1-3 | BARCELONA |  | ||
| 26.09.2004 |  | REAL ZARAGOZA | 4-3 | LEVANTE |  | ||
| 26.09.2004 |  | SEVILLA | 2-1 | REAL SOCIEDAD |  | ||
| 26.09.2004 |  | VALENCIA | 2-0 | RACING SANTANDER |  |
