| DATE | HOME | SCORE | AWAY | ||||
| 21.09.2004 |  | REAL MADRID | 1-0 | OSASUNA |  | ||
| 22.09.2004 |  | DEPORTIVO LA CORUÑA | 1-5 | VALENCIA |  | ||
| 22.09.2004 |  | REAL BETIS | 2-1 | ATHLETIC BILBAO |  | ||
| 22.09.2004 |  | GETAFE | 1-0 | ESPANYOL |  | ||
| 22.09.2004 |  | MÁLAGA | 4-1 | NUMANCIA |  | ||
| 22.09.2004 |  | ALBACETE | 0-0 | MALLORCA |  | ||
| 22.09.2004 |  | LEVANTE | 1-0 | ATLÉTICO MADRID |  | ||
| 22.09.2004 |  | VILLARREAL | 0-0 | SEVILLA |  | ||
| 22.09.2004 |  | REAL SOCIEDAD | 0-1 | RACING SANTANDER |  | ||
| 23.09.2004 |  | BARCELONA | 4-1 | REAL ZARAGOZA |  |
