| DATE | HOME | SCORE | AWAY | ||||
| 19.09.2009 |  | DEPORTIVO LA CORUÑA | 2-3 | ESPANYOL |  | ||
| 19.09.2009 |  | MALLORCA | 4-3 | TENERIFE |  | ||
| 19.09.2009 |  | OSASUNA | 0-2 | SEVILLA |  | ||
| 19.09.2009 |  | MÁLAGA | 1-2 | RACING SANTANDER |  | ||
| 19.09.2009 |  | BARCELONA | 5-2 | ATLÉTICO MADRID |  | ||
| 20.09.2009 |  | REAL MADRID | 5-0 | XEREZ |  | ||
| 20.09.2009 |  | ATHLETIC BILBAO | 3-2 | VILLARREAL |  | ||
| 20.09.2009 |  | REAL ZARAGOZA | 1-2 | REAL VALLADOLID |  | ||
| 20.09.2009 |  | VALENCIA | 2-2 | SPORTING GIJÓN |  | ||
| 20.09.2009 |  | ALMERÍA | 1-0 | GETAFE |  |
