| DATE | HOME | SCORE | AWAY | ||||
| 03.11.2007 |  | MALLORCA | 0-2 | VALENCIA |  | ||
| 03.11.2007 |  | SEVILLA | 2-0 | REAL MADRID |  | ||
| 04.11.2007 |  | REAL ZARAGOZA | 2-3 | REAL VALLADOLID |  | ||
| 04.11.2007 |  | RACING SANTANDER | 1-1 | ESPANYOL |  | ||
| 04.11.2007 |  | OSASUNA | 0-2 | GETAFE |  | ||
| 04.11.2007 |  | REAL MURCIA | 0-2 | DEPORTIVO LA CORUÑA |  | ||
| 04.11.2007 |  | LEVANTE | 3-0 | ALMERÍA |  | ||
| 04.11.2007 |  | ATLÉTICO MADRID | 3-4 | VILLARREAL |  | ||
| 04.11.2007 |  | BARCELONA | 3-0 | REAL BETIS |  | ||
| 04.11.2007 |  | ATHLETIC BILBAO | 2-0 | RECREATIVO HUELVA |  |
