| DATE | HOME | SCORE | AWAY | ||||
| 25.08.2007 |  | REAL MADRID | 2-1 | ATLÉTICO MADRID |  | ||
| 25.08.2007 |  | REAL MURCIA | 2-1 | REAL ZARAGOZA |  | ||
| 25.08.2007 |  | SEVILLA | 4-1 | GETAFE |  | ||
| 26.08.2007 |  | ATHLETIC BILBAO | 0-0 | OSASUNA |  | ||
| 26.08.2007 |  | RACING SANTANDER | 0-0 | BARCELONA |  | ||
| 26.08.2007 |  | MALLORCA | 3-0 | LEVANTE |  | ||
| 26.08.2007 |  | VALENCIA | 0-3 | VILLARREAL |  | ||
| 26.08.2007 |  | DEPORTIVO LA CORUÑA | 0-3 | ALMERÍA |  | ||
| 26.08.2007 |  | ESPANYOL | 0-1 | REAL VALLADOLID |  | ||
| 26.08.2007 |  | RECREATIVO HUELVA | 1-1 | REAL BETIS |  |
