| DATE | HOME | SCORE | AWAY | ||||
| 01.04.2006 |  | BARCELONA | 1-1 | REAL MADRID |  | ||
| 01.04.2006 |  | REAL SOCIEDAD | 3-0 | MÁLAGA |  | ||
| 01.04.2006 |  | REAL ZARAGOZA | 0-1 | VILLARREAL |  | ||
| 02.04.2006 |  | ATLÉTICO MADRID | 0-3 | CELTA DE VIGO |  | ||
| 02.04.2006 |  | REAL BETIS | 2-1 | SEVILLA |  | ||
| 02.04.2006 |  | DEPORTIVO ALAVÉS | 0-0 | ATHLETIC BILBAO |  | ||
| 02.04.2006 |  | DEPORTIVO LA CORUÑA | 2-0 | RACING SANTANDER |  | ||
| 02.04.2006 |  | MALLORCA | 0-0 | ESPANYOL |  | ||
| 02.04.2006 |  | OSASUNA | 0-4 | GETAFE |  | ||
| 02.04.2006 |  | VALENCIA | 5-3 | CÁDIZ |  |
