| DATE | HOME | SCORE | AWAY | ||||
| 18.03.2006 |  | GETAFE | 1-2 | DEPORTIVO LA CORUÑA |  | ||
| 18.03.2006 |  | REAL SOCIEDAD | 0-2 | BARCELONA |  | ||
| 18.03.2006 |  | VILLARREAL | 1-1 | ATLÉTICO MADRID |  | ||
| 19.03.2006 |  | CÁDIZ | 0-0 | DEPORTIVO ALAVÉS |  | ||
| 19.03.2006 |  | CELTA DE VIGO | 0-1 | ATHLETIC BILBAO |  | ||
| 19.03.2006 |  | ESPANYOL | 2-4 | OSASUNA |  | ||
| 19.03.2006 |  | MÁLAGA | 0-1 | REAL ZARAGOZA |  | ||
| 19.03.2006 |  | RACING SANTANDER | 2-1 | VALENCIA |  | ||
| 19.03.2006 |  | REAL MADRID | 0-0 | REAL BETIS |  | ||
| 19.03.2006 |  | SEVILLA | 1-1 | MALLORCA |  |
