| DATE | HOME | SCORE | AWAY | ||||
| 04.02.2006 |  | MÁLAGA | 2-1 | ATHLETIC BILBAO |  | ||
| 04.02.2006 |  | REAL MADRID | 4-0 | ESPANYOL |  | ||
| 04.02.2006 |  | DEPORTIVO LA CORUÑA | 0-1 | VALENCIA |  | ||
| 05.02.2006 |  | VILLARREAL | 1-1 | CÁDIZ |  | ||
| 05.02.2006 |  | SEVILLA | 0-1 | OSASUNA |  | ||
| 05.02.2006 |  | REAL ZARAGOZA | 4-3 | REAL BETIS |  | ||
| 05.02.2006 |  | BARCELONA | 1-3 | ATLÉTICO MADRID |  | ||
| 05.02.2006 |  | REAL SOCIEDAD | 2-1 | MALLORCA |  | ||
| 05.02.2006 |  | GETAFE | 2-2 | DEPORTIVO ALAVÉS |  | ||
| 05.02.2006 |  | RACING SANTANDER | 0-1 | CELTA DE VIGO |  |
