| DATE | HOME | SCORE | AWAY | ||||
| 16.10.2004 |  | DEPORTIVO LA CORUÑA | 2-1 | GETAFE |  | ||
| 16.10.2004 |  | REAL BETIS | 1-1 | REAL MADRID |  | ||
| 16.10.2004 |  | ESPANYOL | 0-1 | BARCELONA |  | ||
| 17.10.2004 |  | ATHLETIC BILBAO | 1-0 | MÁLAGA |  | ||
| 17.10.2004 |  | OSASUNA | 3-2 | ALBACETE |  | ||
| 17.10.2004 |  | NUMANCIA | 1-3 | LEVANTE |  | ||
| 17.10.2004 |  | MALLORCA | 1-1 | VILLARREAL |  | ||
| 17.10.2004 |  | REAL ZARAGOZA | 2-1 | REAL SOCIEDAD |  | ||
| 17.10.2004 |  | ATLÉTICO MADRID | 1-0 | RACING SANTANDER |  | ||
| 17.10.2004 |  | VALENCIA | 1-2 | SEVILLA |  |
