| DATE | HOME | SCORE | AWAY | ||||
| 11.09.2004 |  | ATHLETIC BILBAO | 2-2 | VALENCIA |  | ||
| 11.09.2004 |  | REAL MADRID | 1-0 | NUMANCIA |  | ||
| 11.09.2004 |  | BARCELONA | 2-0 | SEVILLA |  | ||
| 12.09.2004 |  | DEPORTIVO LA CORUÑA | 1-3 | OSASUNA |  | ||
| 12.09.2004 |  | REAL BETIS | 1-4 | ESPANYOL |  | ||
| 12.09.2004 |  | GETAFE | 1-2 | MALLORCA |  | ||
| 12.09.2004 |  | MÁLAGA | 0-0 | REAL ZARAGOZA |  | ||
| 12.09.2004 |  | ALBACETE | 0-2 | ATLÉTICO MADRID |  | ||
| 12.09.2004 |  | LEVANTE | 3-1 | RACING SANTANDER |  | ||
| 12.09.2004 |  | VILLARREAL | 0-0 | REAL SOCIEDAD |  |
