| DATE | HOME | SCORE | AWAY | ||||
| 13.09.2003 |  | REAL MADRID | 7-2 | REAL VALLADOLID |  | ||
| 13.09.2003 |  | RACING SANTANDER | 0-1 | REAL SOCIEDAD |  | ||
| 13.09.2003 |  | SEVILLA | 1-2 | DEPORTIVO LA CORUÑA |  | ||
| 13.09.2003 |  | CELTA DE VIGO | 0-2 | REAL BETIS |  | ||
| 14.09.2003 |  | ALBACETE | 1-2 | BARCELONA |  | ||
| 14.09.2003 |  | OSASUNA | 1-0 | ATLÉTICO MADRID |  | ||
| 14.09.2003 |  | ESPANYOL | 1-2 | VILLARREAL |  | ||
| 14.09.2003 |  | REAL ZARAGOZA | 3-0 | REAL MURCIA |  | ||
| 14.09.2003 |  | ATHLETIC BILBAO | 4-0 | MALLORCA |  | ||
| 14.09.2003 |  | VALENCIA | 1-0 | MÁLAGA |  |
